坡缕石粘土固定辣根过氧化酶处理硝基酚废水     

舒林  彭书传  刘海波  鲍腾  刘文静 《岩石矿物学杂志》2011,30(6):1063-1068

以坡缕石粘土、淀粉、水玻璃为原料,研究了固定化酶载体的制备工艺,探究了固定化酶载体在辣根过氧化酶(HRP)降解硝基酚废水中的作用,并探讨了反应时间、酶浓度、H2O2及硝基酚浓度对降解效果的影响。结果表明,固定化酶载体的最佳制备工艺为:水玻璃12%,淀粉20%,煅烧温度550℃,煅烧时间2 h;固定化酶对硝基酚的去除效果明显高于原酶;固定化酶去除水中硝基酚的最佳反应条件为:反应时间1.5 h,加酶量150 U,H2O2浓度0.12%,硝基酚浓度100 mg/L;固定化酶重复使用7次后对硝基酚的去除率仍高于60%。  相似文献   

基于改进的两步移动搜索法的山区医疗服务空间可达性——以重庆市石柱县为例   总被引：3，自引：3，他引：0  

邓丽  邵景安  郭跃  徐新良 《地理科学进展》2015,34(6)

针对贫困山区医疗资源短缺、分布不均衡、服务能力差等问题,以重庆市石柱县为例,基于自然村尺度,采用改进的两步移动搜索法,从供需角度分析研究区医疗服务空间可达性特征。设置不同的时间阻抗进行敏感性分析,探究可达性变化规律。通过对石柱县医疗资源空间布局的均衡性评价,为山区未来医疗布局的合理规划与医疗标准的配备提供决策依据。结果表明:1石柱县整体医疗服务可达性差,低于重庆市平均水平。2县域医疗资源布局不均衡,空间差异明显。高值区主要集中在方斗山中低山区和黄水镇,低值区主要集中在南部中山区,两极分异明显。3医院的规模、级别,道路的等级、疏密对可达性有一定的影响:靠近县城的乡镇、路网密集的地方可达性一般较好。4随着出行阻抗的增大,医疗服务的可达性随之变好,边缘乡镇的可达性随之变差,可达性值变化幅度减缓,医疗服务空间可达性分异变小;医疗资源配备充足的乡镇,随着时间阻抗增加,对周边乡镇可达性的影响增强。  相似文献   

The influence of freeze-thaw cycles on the granulometric composition of Moscow morainic clay   总被引：2，自引：0，他引：2  

Ze Zhang  Vadim V. Pendin  WenJie Feng  ZhongQiong Zhang 《寒旱区科学》2015,7(3):199-205

The freeze-thaw cycling process considerably changes the composition,structure,and properties of soils.Since the grain size is the most important factor in determining soil characteristics,our current research primarily aims to investigate dynamic changes of the soil fraction when exposed to freeze-thaw conditions.We observed two series of Moscow morainic clayey specimens(g QmII):(I) the original series,and(II) the remolded series.We subjected each series of soil specimens to different frequencies of freeze-thaw cycles(3,6,20,and 40 cycles),and we used granulometric tests to analyze both series before and after exposure to freeze-thaw conditions.As a result of our experiments,the granulometric compositions tended to be distributed evenly after 40 freeze-thaw processes(i.e.,content of fraction for 0.1–0.05 mm was increased after 40 freeze-thaw cycles) because the division of coarse grains and the aggregation of fine grains were synchronized during the freeze-thaw process.The soil grains in both series changed bi-directionally.In the original series,changes of the sand grains were conjugated with the clay grains,and in the remolded series,changes of the sand grains were conjugated with the silt grains,because potential energy difference caused the division and aggregation processes to relate to the counteraction process.The even distribution of soil grain size indicated the state of equilibrium or balance.The granulometric compositions were altered the most during the sixth freeze-thaw cycle,because the coefficient of the intensity variation of the grain fineness(Kvar) had its maximum value at that time.  相似文献   

楚科奇海盆M04柱晚更新世以来沉积古环境记录   总被引：1，自引：0，他引：1  

章伟艳  于晓果  刘焱光  金路  叶黎明  许冬  边叶萍  张德玉  姚旭莹  张富元 《海洋学报》2015,37(7):85-96

对"中国第五次北极科考"采自楚科奇海盆的M04柱进行粒度、冰筏碎屑、黏土矿物、岩心XRF扫描、沉积物颜色分析,初步建立了楚科奇海盆晚更新世MIS4期以来的沉积地层框架。MIS4期以来,楚科奇海盆M04柱沉积物粒度和黏土矿物组成具有明显的冰期/间冰期变化特征,冰期沉积物粒度分布以双峰态为主,由洋流搬运和海冰搬运沉积组分组成,伊利石含量高、高岭石含量低;间冰期沉积物具有三峰态粒度分布特征,由海冰搬运、洋流搬运和冰山搬运沉积组分组成,伊利石含量低、高岭石含量高。通过M04柱黏土矿物组合类型与北冰洋边缘海盆的表层沉积物黏土矿物组合类型对比表明,晚更新世以来楚科奇海盆沉积环境发生显著变化:温暖的间冰期受波弗特涡流驱动,波弗特海为研究区的物源输入提供了主要贡献;寒冷的冰期表层环流呈反向输运,细颗粒物源碎屑以东西伯利亚海的输入为主。  相似文献   

遥感尺度内涵及遥感像元尺度效应分析的改进分形方法     

冯桂香  明冬萍  闫东阳 《测绘学报》2015,(Z1)

本文首先分析了遥感影像尺度的三层次内涵。重点针对遥感像元尺度,分析了遥感像元尺度效应及其分形机理,由于现有分形方法没有考虑影像本身尺度(空间分辨率),造成尺度间分形维数的比较时像元尺度效应变化难以有效反映,本文针对此问题提出了基于表面积的加窗分形布朗运动和加窗双层地毯两种改进分形方法。为验证改进分形方法的可靠性,采用了不同像元尺度下系列监督分类进行验证。试验结果表明,每种地物的分维数都随着空间分辨率的降低或像元尺度的缩小,呈总体下降趋势,在某些特征尺度上会出现预示着某些地物结构的拐点,这些拐点对观测该区域地物具有一定指示意义。系列监督分类精度也一定程度上证明了以上两种改进分形方法在分析尺度效应中的可行性。因此本文的方法对于分析遥感像元尺度效应和探索地物尺度聚合规律具有一定的理论意义。  相似文献   

粉质黏土堤防漫溢溃决试验          下载免费PDF全文

魏红艳  余明辉  李义天  吴松柏 《水科学进展》2015,26(5):668-675

为研究粉质黏土堤防漫溢溃决破坏过程及其对水流要素和土体性质的响应规律,以河道流量、筑堤土体含水率和孔隙率为变量,在弯道水槽中开展了9组堤防漫溢溃决概化试验.通过试验发现,粉质黏土堤漫溢溃决溃口发展过程可分为垂向侵蚀和横向扩宽两个阶段,垂向侵蚀阶段以"陡坎"后退为主要形式;筑堤土体含水率与孔隙率不仅影响了溃口垂向侵蚀以及横向扩宽速度,而且决定了溃口最终形态,河道流量主要影响堤防溃口的横向扩宽速度;溃口处流速以及下游水位变化受溃口高度的制约.拟合得到土体黏聚力与土体含水率、孔隙率的相关关系式;通过试验数据提出了由土体黏聚力和水流参数表达的"陡坎"侵蚀后退速度计算公式,证明具有一定合理性.  相似文献   

Characterisation of hydroclimatological trends and variability in the Lake Naivasha basin,Kenya          下载免费PDF全文

Vincent Omondi Odongo  Christiaan van der Tol  Pieter R. van Oel  Frank M. Meins  Robert Becht  Japheth Onyando  Zhongbo Su 《水文研究》2015,29(15):3276-3293

Recent hydro‐climatological trends and variability characteristics were investigated for the Lake Naivasha basin with the aim of understanding the changes in water balance components and their evolution over the past 50 years. Using a Bayesian change point analysis and modified Mann–Kendall tests, time series of annual mean, maximum, minimum, and seasonal precipitation and flow, as well as annual mean lake volumes, were analysed for the period 1960–2010 to uncover possible abrupt shifts and gradual trends. Double cumulative curve analysis was used to investigate the changes in hydrological response attributable to either human influence or climatic variability. The results indicate a significant decline in lake volumes at a mean rate of 9.35 × 10⁶ m³ year^?1. Most of the river gauging stations showed no evidence of trends in the annual mean and maximum flows as well as seasonal flows. Annual minimum flows, however, showed abrupt shifts and significant (upward/downward) trends at the main outlet stations. Precipitation in the basin showed no evidence of abrupt shifts, but a few stations showed gradual decline. The observed changes in precipitation could not explain the decline in both minimum flows and lake volumes. The findings show no evidence of any impact of climate change for the Lake Naivasha basin over the past 50 years. This implies that other factors, such as changes in land cover and infrastructure development, have been responsible for the observed changes in streamflow and lake volumes. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions          下载免费PDF全文

Bastian Knorr  Piotr Maloszewski  Florian Krämer  Christine Stumpp 《水文研究》2016,30(6):914-926

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

华北克拉通南缘石炭系本溪组铁-铝黏土矿物质来源: 以河南三门峡大安铝黏土矿床为例^*          下载免费PDF全文

刘学飞  王庆飞  马遥  李中明  赵利华  周智慧  刘百顺  马欣莉 《古地理学报》2020,22(5):965-976

华北克拉通在中奥陶世至晚石炭世期间一直出露地表,经历了长期的风化作用,形成大规模的铁-铝黏土矿,其成矿物源一直是研究的热点,尤其是本溪组底部铁矿和铁质黏土矿与上部铝黏土矿是否为同一来源尚未查清。本研究选取克拉通南缘大安铝黏土矿床作为研究对象,展开微区矿物及元素地球化学组成分析,进一步探讨铁-铝黏土矿物质来源。大安矿床内含矿岩系自下而上包括铁质黏土岩、铝土矿、铝质黏土矿;局部喀斯特高地缺失铝土矿,铝质黏土矿直接覆盖于铁质黏土岩之上。铁质黏土岩在洼地以菱铁矿、黄铁矿和伊利石为主,在隆起区以赤铁矿、伊利石和高岭石为主。铝土矿以硬水铝石、伊利石和锐钛矿为主;铝质黏土矿主要矿物为伊利石。矿物微区分析在黏土矿底部发现大量的碳化硅和少量自然硅、硅铁矿、铬铁矿;区域对比揭示北秦岭造山带内商丹缝合带和二郎坪群中的蛇绿岩为铝黏土矿形成提供了成矿物质。本溪组底部铁质黏土与上部铝黏土矿稳定元素比率(例如Zr/TiO₂、Hf/TiO₂、Nb/TiO₂、Ta/TiO₂)存在明显差异,揭示二者为不同来源: 底部铁质黏土岩和铁矿层为底板碳酸盐岩原地风化的产物;而上部铝黏土矿是异地搬运物,北秦岭造山带在晚石炭世的整体抬升为华北铝黏土矿形成提供了重要的成矿物质。  相似文献   

Climatic signals in lacustrine deposits of the Upper Yacoraite Formation,Western Argentina: Evidence from clay minerals,analcime, dolomite and fibrous calcite     

João Paulo B. Gomes  Rodrigo B. Bunevich  Sandra N. Tonietto  Daisy B. Alves  Julice F. Santos  Fiona F. Whitaker 《Sedimentology》2020,67(5):2282-2309

Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits.  相似文献